New type of solar cell uses an inorganic nanowire structure
April 13, 2011
Researchers from Xiamen University in China and the University of North Carolina at Charlotte have successfully fabricated and tested a new type of solar cell using an inorganic nanowire structure.
The researchers created zinc oxide (ZnO) nanowires with a zinc selenide (ZnSe) coating to form a material structure known as a type-II heterojunction, which has a significantly lower bandgap than either of the original materials. Arrays of the structured nanowires were subsequently able to absorb light from the visible and near-infrared wavelengths.
The nanowires were created by first growing an array of six-sided zinc oxide crystal “wires” from a thin film of the same material, using vapor deposition. The technique created a forest of smooth-sided needle-like zinc oxide crystals with uniform diameters (40 to 80 nanometers) along their length (approximately 1.4 micrometers).
A somewhat rougher zinc selenide shell was then deposited to coat all the wires. Finally, an indium tin oxide (ITO) film was bonded to the zinc selenide coating, and an indium probe was connected to the zinc oxide film, creating contacts for any current generated by the cell.
The researchers showed the photoresponse threshold of the nanowire structure to be 1.6 eV, capable of absorbing light wavelengths from the ultraviolet to the near infrared.
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